Synthesis and characterization of cyclohexene oxide functional polystyrene macromonomers by ATRP and their use in photoinitiated cationic polymerization

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dc.contributor.authorDegirmenci, Mustafa
dc.contributor.authorIzgin, Oner
dc.contributor.authorAcikses, Aslisah
dc.contributor.authorGenli, Nasrettin
dc.date.accessioned2026-08-12T17:45:50Z
dc.date.issued2010
dc.departmentFırat Üniversitesi
dc.description.abstractIn this study, a novel well-defined macromonomer of epoxy end-functionalized polystyrene was synthesized by atom transfer radical polymerization (ATRP). The compound 3-cyclohexenylmethyl-2-bromopropanoate was synthesized by the condensation of 3-cyclohexene-1-methanol with 2-bromopropanoyl bromide. Subsequently, the epoxidation of the obtained 3-cyclohexenylmethyl-2-bromopropanoate using 3-chloroperoxybenzoic acid results in a new epoxy functional ATRP initiator. The ATRP of styrene (St) in bulk at 110 degrees C, by means of this initiator in conjunction with the cuprous complex Cu(I)Br/bipyridine, yields a well-defined macromonomer of polystyrene with an epoxy end group. GPC, IR, and H-1 NMR analyses revealed that a low-polydispersity polystyrene with the desired functionality at the end of the chain was obtained. The photoinduced cationic polymerization of this macromonomer yielded graft and block copolymers. (C) 2009 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipHarran University, the Scientific Research Council (HOBAK); Firat University Scientific Research Projects Unit (FOBAP)
dc.description.sponsorshipThe authors would like to thank Harran University, the Scientific Research Council (HOBAK) and Firat University Scientific Research Projects Unit (FOBAP) for financial support.
dc.identifier.doi10.1016/j.reactfunctpolym.2009.09.010
dc.identifier.endpage34
dc.identifier.issn1381-5148
dc.identifier.issn1873-166X
dc.identifier.issue1
dc.identifier.scopus2-s2.0-70749093161
dc.identifier.scopusqualityQ1
dc.identifier.startpage28
dc.identifier.urihttps://doi.org/10.1016/j.reactfunctpolym.2009.09.010
dc.identifier.urihttps://hdl.handle.net/11508/60849
dc.identifier.volume70
dc.identifier.wosWOS:000274703200004
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofReactive & Functional Polymers
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20260511
dc.subjectAtom transfer radical polymerization (ATRP)
dc.subjectFunctional polymer
dc.subjectMacromonomer
dc.subjectFree radical promoted cationic polymerization
dc.subjectCopolymerization
dc.titleSynthesis and characterization of cyclohexene oxide functional polystyrene macromonomers by ATRP and their use in photoinitiated cationic polymerization
dc.typeArticle

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