Photoinduced changes of the optical parameters of thin films from Ge 30.8As5.7S63.5 glass

Abstract

Extremely high irreversible changes of the optical parameters have been found after long time illumination of thin films thermally evaporated from Ge2As3-AsS3 glass, which belongs to the Ge 2As3-AsS3 line. Illumination of virgin films leads to a blue shift of the absorption edge, photo-bleaching (PB). Changes of the optical band gap, Eg up to about 600 meV (?27%), of the refractive index, n up to 0.2 (?9.5%), as well as the thickness increase ?70 nm (11%) have been obtained. The dependences of the parameters of the irreversible PB on the film thickness (between 0.4 - 1.4 ?m) and the time of illumination (up to 3h) have been investigated. The magnitude of the irreversible PB is compared with that of the irreversible thermo-bleaching after annealing near to the glass transition temperature, as well as with that of the reversible photo-darkening of the annealed films. The reasons for the appearance of such high photo-induced changes, which are interesting for practical uses, are discussed.