Design of Fe-35Ni/PCL nanocomposites with coupled magnetic and shape memory properties

Abstract

In this study, poly(& varepsilon;-caprolactone) (PCL)-based nanocomposite films reinforced with a Fe-35%Ni alloy, which possesses a low coefficient of thermal expansion and distinct magnetic properties, were produced. The composites were prepared using the solvent casting method, with the Fe-Ni alloy incorporated into the PCL matrix at different weight ratios (10%-50%). The structural, morphological, thermal, and magnetic properties of the resulting nanocomposites were comprehensively investigated using FTIR (Fourier transform infrared spectroscopy), XRD (X-ray diffraction), SEM (scanning electron microscopy/energy dispersive x-ray spectroscopy), differential scanning calorimetry, TGA (Thermogravimetric analysis) ve (vibrating sample Magnetometry). FTIR results indicated that the Fe-Ni addition does not form chemical bonds with the PCL matrix and that the composite structure is formed through physical interactions. XRD analyses confirmed that the semi-crystalline structure of PCL is preserved and that the Fe-Ni alloy exhibits a face-centered cubic (FCC) crystal structure. SEM images revealed that while a homogeneous distribution is achieved at low doping levels, partial agglomeration occurs at high levels. Thermal analyses showed that Fe-Ni particles increase the degree of crystallization through a nucleation effect and provide a significant increase in melting temperature and crystallinity values, particularly in the 10%-40% range. TGA results revealed that the thermal stability of the composites increased and their decomposition behavior became multi-stage. Magnetic measurements showed that the saturation magnetization increased significantly with increasing Fe-Ni content, and the composites acquired ferromagnetic character. Furthermore, it was determined that the developed composites exhibit distinct shape memory behavior and can return to their original form upon thermal stimulation. The findings indicate that Fe-35%Ni-doped PCL nanocomposites are a promising candidate for multifunctional applications due to their enhanced thermal, magnetic, and smart material properties.