EMI-shielding response of GO/Fe3O4/polypyrrole(PPy)/thermoplastic polyurethane (TPU) composites

dc.contributor.authorKaftelen-Odabasi, H.
dc.contributor.authorRuiz-Perez, F.
dc.contributor.authorOdabasi, A.
dc.contributor.authorHelhel, S.
dc.contributor.authorLopez-Estrada, S. M.
dc.contributor.authorCaballero-Briones, F.
dc.date.accessioned2026-08-12T18:10:42Z
dc.date.issued2024
dc.departmentFırat Üniversitesi
dc.description.abstractIn the present study, thermoplastic polyurethane was reinforced with GO/Fe3O4/PPy nanocomposites with varying GO:Fe3O4 ratio to develop high-performance electromagnetic interference (EMI) shields. GO/Fe3O4/PPy fillers were prepared by adding polypyrrole (PPy) nanotubes, synthesized by the soft-template method from oxidative polymerization of pyrrole, to graphene oxide decorated with Fe3O4 nanoparticles prepared by a sonochemical method. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectroscopy were performed to reveal the structural and morphological properties of GO/Fe3O4/PPy nanofillers, and the structure and thermal properties of the GO/Fe3O4/PPy/TPU nanocomposites was studied by cryofracture SEM and thermogravimetry (TGA). The effect of GO:Fe3O4 ratio on the electrical conductivity, magnetic permeability, permittivity, and electromagnetic-wave-shielding performance of GO/Fe3O4/PPy/TPU nanocomposites was investigated in the Xband frequency range. The maximum EMI efficiency was 4.81 dB with increasing GO:Fe3O4 ratio in GO/Fe3O4/ PPy/TPU composites, with blocking of 66.72 % of the incident electromagnetic wave.
dc.description.sponsorshipFirat University [SHY 19.01, SHY 23.01]; SIP-IPN [2024-0907]; CONACYT Frontier Science [2019-40798]; CONACYT [2009-01-123913, 2022-321595, 292692, 294643, 188345, 204822]; FOMIX-Yucatan [2008-108160]; CONACYT LAB [2009-01-123913, 292692, 294643, 188345, 204822]
dc.description.sponsorshipThis work was supported by the Firat University would like to thank the funding through the grant numbers SHY 19.01 and SHY 23.01. This work was partially financed by the projects SIP-IPN 2024-0907, CONACYT Frontier Science 2019-40798 and CONACYT Infrastructure 2022-321595. The SEM and XRD analyses of GO-Fe3O4-PPy composites were carried out in the National Laboratory of Nano and Biomaterials (LANNBIO CONAHCYT) at CINVESTAV Merida, financed by the projects FOMIX-Yucatan 2008-108160, CONACYT LAB-2009-01-123913, 292692, 294643, 188345 and 204822. Authors thank Dr. Patricia Quintana for access to LANNBIO, MSc. Daniel Aguilar for obtaining diffractograms, MSc. Mario Herrera Salvador for corrective diffractometer maintenance, and Dr. Victor Rejon for SEM acquisition. Dr. Lourdes Palma-Tirado at INB-UNAM Juriquilla is acknowledged for TEM measurements of the GO-Fe3O4-PPy composites. The authors thank Ravago Co. for providing the TPU granules. The authors acknowledge Research Assistant M. O zdemir for helping hot pressing of TPU composites.
dc.identifier.doi10.1016/j.jestch.2024.101753
dc.identifier.issn2215-0986
dc.identifier.orcid0000-0003-1111-5420
dc.identifier.orcid0000-0002-1401-3297
dc.identifier.orcid0000-0001-6867-0121
dc.identifier.orcid0000-0003-4340-1050
dc.identifier.scopus2-s2.0-85196650815
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.jestch.2024.101753
dc.identifier.urihttps://hdl.handle.net/11508/63395
dc.identifier.volume55
dc.identifier.wosWOS:001260327200001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier - Division Reed Elsevier India Pvt Ltd
dc.relation.ispartofEngineering Science and Technology-an International Journal-Jestech
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20260511
dc.subjectElectromagnetic shielding
dc.subjectThermoplastic composites
dc.subjectShielding efficiency
dc.subjectGO/Fe (3) O (4) /PPy nanofillers
dc.titleEMI-shielding response of GO/Fe3O4/polypyrrole(PPy)/thermoplastic polyurethane (TPU) composites
dc.typeArticle

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