QUANTUM CALCULATIONS OF HARMONIC-VIBRATIONAL TRANSITION-PROBABILITIES IN COLLINEAR X2Y2+X2Z2 COLLISIONS

Abstract

Quantum-mechanical calculations of harmonic-vibrational transition probabilities were reported for nonreactive collinear X2Y2 + X2Z2 collisions. Calculations are carried out for C2H2 + C2H2, C2H2 + C2D2 and C2D2 + C2D2 systems. The dependence of transition probabilities on doubly and triply degenerate states was investigated.