Influence of Congored on the Optical, Dielectric and Thermal Behavior of Polymethyl Methacrylate and Polyvinyl Chloride

Abstract

Polymethyl methacrylate (PMMA)/Congo Red (CR) and polyvinyl chloride (PVC)/CR composite films were prepared on optical glass by the drop method for optical measurements and also prepared as tablets under pressure for dielectrical measurements. The optical transmission spectra measurements for PMMA and PVC film doped with CR showed a highly absorption in the ultraviolet-visible (UV-Vis) optical range (at 353 nm and 518 nm) and considerably blocking in broad visible range (190 nm-640 nm). PMMA/CR and PVC/CR composite films containing congo red at a concentration of 1 wt% showed maximum absorption bands at 290 nm and 416 nm, but their transmittance percentages were reasonably reduced compared to those of pure PMMA and PVC. Both of composites indicated high transmittances between 640 nm and 800 nm. The optical constants of the PMMA/CR and PVC/CR composite films such as optical band energy gaps (Eg) estimated using Tauc's model, refractive index and reflectance (%) were calculated. UV-Vis, Fourier transform infrared spectroscopy (FTIR) and Thermogravimetry Analysis (TGA) measurements were used to confirm the breakdown of the -N = N- azo group bonds attached to the aromatic ring as a result of thermal decomposition of CR at 500 degrees C, and it was suggested that N2 gas was eliminated from the CR above 360 degrees C. The dielectric plots showed that the dielectric constant increased when the CR is doped up to 70 wt% in the polymer matrices. A further increase in the doping concentration of CR resulted in an increase of the dielectric constant. The dielectric constant decreased with an increase in the frequency for all of the samples. The ac (alternating current) conductivity values of PMMA and PVC showed an increase with increasing CR dopant in the polymer composites, while the ac conductivity values were found to be values between those of the pure polymers and CR.