REACTIONS OF METHOXY-SUBSTITUTED AROMATIC COAL MODELS IN SUPERCRITICAL SOLVENTS

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dc.contributor.authorPEHLIVAN, D
dc.contributor.authorOLCAY, A
dc.date.accessioned2026-08-12T17:01:24Z
dc.date.issued1994
dc.departmentFırat Üniversitesi
dc.description.abstractReactions of alpha- and beta-methoxy naphthalene and anisole in supercritical benzene and toluene were studied at 420-degrees-C and 3.9-4.4 MPa pressure. The decomposition of these lower rank coal related model compounds in both solvents was found to obey the first order rate law. While naphthols were present in the reaction mixture of methoxy naphthalenes, phenol and cresoles were present in that of anisole. In addition to these products, diphenyl or dibenzyl was also present in the reaction mixture of supercritical benzene or toluene, respectively. The reactions between models and solvents might be explained by free radical and intermolecular rearrangement reaction pathways.
dc.identifier.doi10.1080/08843759408916184
dc.identifier.endpage388
dc.identifier.issn0884-3759
dc.identifier.issue3
dc.identifier.startpage375
dc.identifier.urihttps://doi.org/10.1080/08843759408916184
dc.identifier.urihttps://hdl.handle.net/11508/47667
dc.identifier.volume12
dc.identifier.wosWOS:A1994NJ46100001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherMarcel Dekker Inc
dc.relation.ispartofFuel Science & Technology International
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20260511
dc.subjectBenzyl Phenyl Ether
dc.titleREACTIONS OF METHOXY-SUBSTITUTED AROMATIC COAL MODELS IN SUPERCRITICAL SOLVENTS
dc.typeArticle

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