Investigation of the thermal properties of [Cd(hydet-en)2Pd(CN)4] and [Zn(hydet-en)2Pd(CN)4] single crystals

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dc.contributor.authorYakuphanoğlu, Fahrettin
dc.contributor.authorKaradag, A.
dc.contributor.authorSekerci, M.
dc.date.accessioned2026-08-12T17:29:32Z
dc.date.issued2006
dc.departmentFırat Üniversitesi
dc.description15th Annual Workshop and Exhibition of the Canadian-Thermal-Analysis-Society -- MAY 17-18, 2005 -- Boucheville, CANADA
dc.description.abstractThermal properties of the single crystals have been investigated by thermogravimetry (TG) and differential scanning calorimetry (DSC) techniques. The thermodynamic parameters such as activation energy and enthalpy and thermal stability temperature of the samples were calculated from the differential thermal analysis (DTA) and TG data. The activation energies for first peak of DTA curves were found as 496.65 (for Cd-Pd) and 419.37 kJ mol(-1) (for Zn-Pd). For second peak, activation energies were calculated 116.56 (for Cd-Pd) and 173.96 kJ mol(-1) (for Zn-Pd). The thermal stability temperature values of the Cd-Pd and Zn-Pd compounds at 10 degrees C min(-1) heating rate are determined as approximately 220.7 and 203 degrees C, respectively. The TG results suggest that thermal stability of the Cd-Pd complex is higher than that of the Zn-Pd complex.
dc.description.sponsorshipCanadian Thermal Anal Soc
dc.identifier.doi10.1007/s10973-005-7297-0
dc.identifier.endpage731
dc.identifier.issn1388-6150
dc.identifier.issn1588-2926
dc.identifier.issue3
dc.identifier.orcid0000-0003-4676-683X
dc.identifier.orcid0000-0002-7730-645X
dc.identifier.scopus2-s2.0-33845459096
dc.identifier.scopusqualityQ1
dc.identifier.startpage727
dc.identifier.urihttps://doi.org/10.1007/s10973-005-7297-0
dc.identifier.urihttps://hdl.handle.net/11508/55746
dc.identifier.volume86
dc.identifier.wosWOS:000242660100023
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.publicationcategoryKonferans Öğesi - Uluslararası - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20260511
dc.subjectkinetics parameters
dc.subjectsingle crystal
dc.subjectthermal analysis
dc.titleInvestigation of the thermal properties of [Cd(hydet-en)2Pd(CN)4] and [Zn(hydet-en)2Pd(CN)4] single crystals
dc.typeConference Object

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