Influence of Temperatures on the Tautomerism of the N-(1H-imidazoline-2-yl)-1H-benzimidazol-2-amine and Investigation of Its Electrochemical Behaviour

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dc.contributor.authorServi, Suleyman
dc.contributor.authorGenc, Murat
dc.contributor.authorSaydam, Sinan
dc.date.accessioned2026-08-12T17:31:31Z
dc.date.issued2012
dc.departmentFırat Üniversitesi
dc.description.abstractSynthesis of N-(1H-imidazoline-2-yl)-1H-benzimidazol-2-amine was carried out under microwave irradiation (MWI) conditions. Dynamic 1H NMR investigation of N-(1H-imidazoline-2-yl)-1H-benzimidazol-2-amine compound was reported at temperature range of 223333 K in DMF-d7. Some physical parameters, such as coalescence temperature (Tc), the free energy of activation (?G*?) and rate constant (k) values were calculated from its 1H NMR spectra at various temperatures. Electrochemical feature of this compound was investigated by cyclic (CV) and square wave voltammetry (SWV).
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [105T419, 105T240]
dc.description.sponsorshipWe are indebted to the Scientific and Technological Research Council of Turkey (TUBITAK, Project Number: 105T419 and 105T240) for financial support of this work. Thanks are also due to Dr. Ayla Turkekul from Bogazici University for recording 1H NMR spectra at 223-333 K temperatures.
dc.identifier.doi10.1002/cjoc.201100103
dc.identifier.endpage404
dc.identifier.issn1001-604X
dc.identifier.issn1614-7065
dc.identifier.issue2
dc.identifier.orcid0000-0003-1224-4128
dc.identifier.orcid0000-0003-1531-5454
dc.identifier.scopus2-s2.0-84857198917
dc.identifier.scopusqualityQ1
dc.identifier.startpage400
dc.identifier.urihttps://doi.org/10.1002/cjoc.201100103
dc.identifier.urihttps://hdl.handle.net/11508/56292
dc.identifier.volume30
dc.identifier.wosWOS:000300674000035
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofChinese Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20260511
dc.subjectbenzimidazole
dc.subjecttautomerism
dc.subjectdynamic NMR
dc.subjectcyclic voltammetry
dc.titleInfluence of Temperatures on the Tautomerism of the N-(1H-imidazoline-2-yl)-1H-benzimidazol-2-amine and Investigation of Its Electrochemical Behaviour
dc.typeArticle

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