Cyclohexene oxide mid-chain functional macromonomer of poly(?-caprolactone): Synthesis, characterization, and photoinitiated cationic homo- and copolymerization

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dc.contributor.authorDegirmenci, Mustafa
dc.contributor.authorAcikses, Aslisah
dc.contributor.authorGenli, Nasrettin
dc.date.accessioned2026-08-12T17:14:42Z
dc.date.issued2012
dc.departmentFırat Üniversitesi
dc.description.abstractIn this study, a novel well-defined epoxy mid-chain functional macromonomer of poly(e-caprolactone) (PCL) has been synthesized by ring-opening polymerization (ROP) of e-caprolactone (e-CL) and epoxidation on workup with 3-chloroperoxybenzoic acid. The ROP of e-CL monomer in bulk at 110 degrees C, by means of a dihydroxy functional initiator namely, 3-cyclohexene-1,1-dimethanol in conjunction with stannous-2-ethylhexanoate, (Sn(Oct)2), yielded a well-defined PCL with a cyclohexene mid-chain group. The epoxidation of the cyclohexene (CH) mid-chain group of PCL was performed using 3-chloroperoxybenzoic acid. GPC, IR, and 1H-NMR analyses revealed that a low-polydispersity macromonomer of PCL with the desired cyclohexene oxide (CHO) functionality at the mid-chain was obtained. The photoinduced cationic polymerizations of this macromonomer yielded comb-shaped and graft copolymers. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
dc.description.sponsorshipFirat University Scientific Research Projects Unit (FUBAP); Harran University, The Scientific Research Council (HUBAK)
dc.description.sponsorshipContract grant sponsors: Firat University Scientific Research Projects Unit (FUBAP); Harran University, The Scientific Research Council (HUBAK).
dc.identifier.doi10.1002/app.33423
dc.identifier.endpage2573
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.issue5
dc.identifier.scopus2-s2.0-82455175694
dc.identifier.scopusqualityQ2
dc.identifier.startpage2567
dc.identifier.urihttps://doi.org/10.1002/app.33423
dc.identifier.urihttps://hdl.handle.net/11508/51937
dc.identifier.volume123
dc.identifier.wosWOS:000298086200001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofJournal of Applied Polymer Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20260511
dc.subjectring-opening polymerization
dc.subjectfunctionalization of polymers
dc.subjectmacromonomers
dc.subjectphotopolymerization
dc.subjectgraft copolymers
dc.titleCyclohexene oxide mid-chain functional macromonomer of poly(?-caprolactone): Synthesis, characterization, and photoinitiated cationic homo- and copolymerization
dc.typeArticle

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